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Charcoal
Charcoal is probably the oldest, or one of the oldest, art materials. It was, after all, what our pre-historic ancestors used while drawing on cave walls! It's ease of manufacture and use make it an essential tool for all artists. Charcoal is an impure form of elemental carbon made by burning selected woods in anaerobic conditions (little or no oxygen), hence, it is chemically fairly simple and stable over millennia. While other art materials may have greater color saturation than charcoal, few will last as long!
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